Custom emissions factors
Where data on CO2 emission factors for specific fuels are not available, an emissions factor can be derived if the carbon content of the fuel is known. This is based on the known relationship between a mass of carbon and the mass of CO2 which is produced on burning together with an assumption of 100% burning efficiency - i.e. 100% carbon converted to CO2.
C to CO2 stoichiometry
During combustion of carbonaceous materials, 1 carbon atom (from the material) combines with 2 oxygen atoms (from the environment), producing CO2. The atomic mass of carbon, C, and oxygen, O, are 12 and 14 respectively, and therefore the molecular mass of CO2 is 44. It follows that the ratio of masses of atomic carbon to CO2 is 44/12, or approximately 3.667. By muliplying a quantity (mass) of carbon by this factor, we can derived the equivalent quantity of CO2 which is produced on combustion.
If the concentration of carbon - or 'carbon content' - of a given material is known, then it is straightforward to calculate the absolute mass of carbon which is burned:
masscarbon = massfuel x %carbon ,
where %carbon is expressed on a decimal basis (i.e. 0-1). For example, if 80% of a particular material comprises carbon, then the quantity of carbon burned is simply the mass of fuel burned multiplied by 0.80. Therefore, if one knows the carbon content of a given fuel and the amount burned, the corresponding CO2 emissions can be calculated thus:
mass CO2 = massfuel x %carbon x 3.667,
where %carbon * 3.667 represents the 'emissions factor' for the given fuel (or material more generally).
Expressing in other units
In some cases, an emissions factor which is applicable to other units of quantity - e.g. energy or volume - are appropriate. These can be derived by using the correct conversion factors.
A 'heating' or 'calorific' value is a value representing the energy contained within a given material or fuel. These are usually expressed in units such as GJ per L or kWh per t. Energy-based emissions can be calculated using a mass-based heating value x
mass CO2 = energy consumed / energyContentfuel x %carbon x 3.667 ,
where energyContentfuel is the heating value for the particular fuel (i.e. energy per mass). Similarly, one can calculate on the basis of volumetric quantities by converting volume into an equivalent mass using a value for material density (i.e. mass per volume):
mass CO2 = volume consumed x densityfuel x %carbon x 3.667,
where densityfuel is the density (i.e. mass per volume) of the given material.
All of these derivations assume 100% conversion of carbon into CO2.